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Magnetic material could help monitor battery life

Yulong Huang (right) holds a lithium-ion battery with a cathode made from magneto-ionic material. Huang and Zheng Li (left), both UB postdoctoral researchers in mechanical and aerospace engineering, are among authors of a new study on the magneto-ionic material.

 Yulong Huang (right) holds a lithium-ion battery with a cathode made from magneto-ionic material. Huang and Zheng Li (left), both UB postdoctoral researchers in mechanical and aerospace engineering, are among authors of a new study on the magneto-ionic material.

From left: Zheng Li and Yulong Huang demonstrate a system for measuring the magnetism of a magneto-ionic material used in a rechargeable lithium-ion battery. Li and Huang, both UB postdoctoral researchers in mechanical and aerospace engineering, are among authors of a new study on the material.

 From left: Zheng Li and Yulong Huang demonstrate a system for measuring the magnetism of a magneto-ionic material used in a rechargeable lithium-ion battery. Li and Huang, both UB postdoctoral researchers in mechanical and aerospace engineering, are among authors of a new study on the material.

A sample of the magneto-ionic material used in a new study.

 A sample of the magneto-ionic material used in a new study.

Scientists use a ferromagnetic resonance testing unit to measure the magnetism of a magneto-ionic material (pictured on the green board below a testing unit probe).

 Scientists use a ferromagnetic resonance testing unit to measure the magnetism of a magneto-ionic material (pictured on the green board below a testing unit probe).

Yulong Huang, UB postdoctoral researcher in mechanical and aerospace engineering, holds a 3D-printed structure containing the magneto-ionic material used in a new study. The ability to print the material in varied shapes could facilitate different applications, scientists say.

 Yulong Huang, UB postdoctoral researcher in mechanical and aerospace engineering, holds a 3D-printed structure containing the magneto-ionic material used in a new study. The ability to print the material in varied shapes could facilitate different applications, scientists say.

From left: Yulong Huang and Zheng Li, both UB postdoctoral researchers in mechanical and aerospace engineering, are among authors of a new study on magneto-ionics.

 From left: Yulong Huang and Zheng Li, both UB postdoctoral researchers in mechanical and aerospace engineering, are among authors of a new study on magneto-ionics.

Shenqiang Ren (center), UB researcher in the Department of Mechanical and Aerospace Engineering, Department of Chemistry and RENEW Institute, led a new study on magneto-ionics. Zheng Li (left) and Yulong Huang (right), postdoctoral researchers in mechanical and aerospace engineering, are among the co-authors.

 Shenqiang Ren (center), UB researcher in the Department of Mechanical and Aerospace Engineering, Department of Chemistry and RENEW Institute, led a new study on magneto-ionics. Zheng Li (left) and Yulong Huang (right), postdoctoral researchers in mechanical and aerospace engineering, are among the co-authors.
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By CHARLOTTE HSU

Published June 16, 2022

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“We believe this is a new way to provide an accurate, fast, responsive sensing of state of charge. ”
Shenqiang Ren, professor of mechanical and aerospace engineering, and chemistry, and core faculty member
UB RENEW Institute

A new study shows how a magnetic material can be used to help monitor the amount of life left in a rechargeable battery before it needs to be recharged.

UB engineer Shenqiang Ren led the project and explains how the system works.

As lithium-ion batteries charge and discharge, lithium ions flow from one side of the battery to the other. With this in mind, Ren’s team built a lithium-ion battery that uses a special material at one end: a compound whose magnetism changes as lithium ions enter or leave it. This makes it possible to measure the battery’s level of charge by tracking changes in the material’s magnetism, Ren says.

The research was published June 13 in the Proceedings of the National Academy of Sciences (PNAS).

“The main goal of this project was working on the magneto-ionics, which uses ions to control the magnetism of materials. As the lithium ions travel in or out of the material we are using, the material will change its magnetization. We can monitor the magnetism, and this enables us to indirectly monitor the lithium ions — the state of charge. We believe this is a new way to provide an accurate, fast, responsive sensing of state of charge,” says Ren, professor of mechanical and aerospace engineering, and of chemistry, and a core faculty member in the UB RENEW Institute.

In addition to Ren, corresponding authors of the study include Yuguang C. Li, UB assistant professor of chemistry; Fei Yao, UB assistant professor of materials design and innovation; and Qimin Yan, Temple University assistant professor of physics. Yong Hu, a UB PhD student in mechanical engineering, was the first author.

The team’s magneto-ionic material is made from vanadium, chromium and cyanide, with an aqua ligand. The paper in PNAS describes the characteristics of the compound that make it ideal for use in rechargeable batteries, and outlines the techniques the scientists used for measuring the material’s changing magnetism in a rechargeable lithium-ion battery.

Additional co-authors of the study include Weiyi Gong in the Temple University Department of Physics; Sichen Wei in the UB Department of Materials Design and Innovation; and Saurabh Khuje, Yulong Huang and Zheng Li in the UB Department of Mechanical and Aerospace Engineering. At UB, the project brought together a collaborative group from the School of Engineering and Applied Sciences, College of Arts and Sciences, and RENEW Institute.

Researchers who contributed to the study are supported by the U.S. Department of Energy, the U.S. Army Research Office and the New York State Energy Research and Development Authority.